Solvatochromic and Ligand Effects in Ultrafast Intramolecular Electron Transfer in Fe-based Molecular Photosensitizers
نویسندگان
چکیده
منابع مشابه
Intramolecular Electron Transfer
In most of the oxidation—reduction reactions involving net electron transfer which have been studied, the experimental results yield only second order rates, and thus reflect the barrier to bringing reactants together as well as that for the electron transfer act itself. Recent advances in synthetic procedures make it possible to measure as an intramolecular or first order process, net electron...
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The quenching of excited singlet methylene blue (IMB + * ) by N,N-dimethylaminomethylferrocene (FcN) in acetonitrile at room temperature has been studied using femtosecond pump-probe absorption spectroscopy. At high FcN concentration static quenching via an intermolecular electron transfer mechanism constitutes the predominating decay channel for l MB + * The time constants of the large amplitu...
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ژورنال
عنوان ژورنال: EPJ Web of Conferences
سال: 2019
ISSN: 2100-014X
DOI: 10.1051/epjconf/201920509029